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Galena

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Galena is the main ore of lead, used since ancient times. Because of its somewhat low melting point, it was easy to liberate by smelting. It typically forms in low-temperature sedimentary deposits.

In some deposits galena contains about 1–2% silver, a byproduct that far outweighs the main lead ore in revenue. Galena deposits often also contain significant amounts of silver as included silver sulfide mineral phases or as limited solid solution within the galena structure. These argentiferous galenas have long been the most important ore of silver.[citation needed]

Galena deposits are found worldwide in various environments. Noted deposits include those at Freiberg in Saxony; Cornwall, the Mendips in Somerset, Derbyshire, and Cumberland in England; the Madan, Rhodope Mountains in Bulgaria; the Sullivan Mine of British Columbia; Broken Hill and Mount Isa in Australia; and the ancient mines of Sardinia. Galena also occurs in North African countries and at Mount Hermon in Northern Israel. In the United States, it occurs most notably in the Mississippi Valley type deposits of the Lead Belt in southeastern Missouri, and in the Driftless Area of Illinois, Iowa and Wisconsin. The economic importance of galena to the early history of the Driftless Area was so great that one of the towns in the region was named Galena, Illinois.

Cubic galena with calcite from Jasper County, Missouri, USA; 5.1 cm × 3.2 cm × 2.8 cm (2.0 in × 1.3 in × 1.1 in)

Galena also was a major mineral of the zinc-lead mines of the tri-state district around Joplin in southwestern Missouri and the adjoining areas of Kansas and Oklahoma. Galena is also an important ore mineral in the silver mining regions of Colorado, Idaho, Utah and Montana. Of the latter, the Coeur d’Alene district of northern Idaho was most prominent.

Galena is the official state mineral of the U.S. states of Missouri and Wisconsin; the former mining communities of Galena, Kansas and Galena, Illinois take their names from deposits of this mineral.

Derbyshire in the UK was one of the main areas where galena was mined.

The largest documented crystal of galena is composite cubo-octahedra from the Great Laxey Mine, Isle of Man, measuring 25 cm × 25 cm × 25 cm (10 in × 10 in × 10 in).

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Copper

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Copper is a chemical element with symbol Cu (from Latin: cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a reddish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement.

Copper is one of the few metals that occur in nature in directly usable metallic form (native metals) as opposed to needing extraction from an ore. This led to very early human use, from c. 8000 BC. It was the first metal to be smelted from its ore, c. 5000 BC, the first metal to be cast into a shape in a mold, c. 4000 BC and the first metal to be purposefully alloyed with another metal, tin, to create bronze, c. 3500 BC.

In the Roman era, copper was principally mined on Cyprus, the origin of the name of the metal, from aes сyprium (metal of Cyprus), later corrupted to сuprum, from which the words copper (English), cuivre (French), cobre (Spanish), Koper (Dutch) and Kupfer (German) are all derived. The commonly encountered compounds are copper(II) salts, which often impart blue or green colors to such minerals as azurite, malachite, and turquoise, and have been used widely and historically as pigments. Copper used in buildings, usually for roofing, oxidizes to form a green verdigris (or patina). Copper is sometimes used in decorative art, both in its elemental metal form and in compounds as pigments. Copper compounds are used as bacteriostatic agents, fungicides, and wood preservatives.

Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the respiratory enzyme complex cytochrome c oxidase. In molluscs and crustaceans, copper is a constituent of the blood pigment hemocyanin, replaced by the iron-complexed hemoglobin in fish and other vertebrates. In humans, copper is found mainly in the liver, muscle, and bone. The adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight.